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The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.(1-3) Absorption spectroscopy was used to measure the behavior of HCHO and OH radicals during a progression from normal combustion to knocking operation. Emission spectroscopic measurements were obtained in the same way that radical added HCO. Radical behavior in preflame reactions was thus examined on the basis of simultaneous measurements, which combined each absorption wavelength with three emission wavelength by using a monochromator and a newly developed polychromator.(4-5) When n-heptane (0 RON) and blended fuel (50 RON) were used as test fuel, it was observed that radical behavior differed between normal combustion and knocking operation and a duration of the preflame reaction was shorter during the progression from normal combustion to a condition of knocking.

There is an urgent need today to improve the thermal efficiency of spark- ignition (SI) engines in order to reduce carbon dioxide emission and conserve energy in an effort to prevent global warming. However, a major obstacle to improving thermal efficiency by raising the compression ratio of SI engine is the easily occurrence of engine knocking. The result of studies done by numerous researchers have shown that knocking is an abnormal combustion in which the unburned gas in the end zone of the combustion chamber autoignites. However, the combustion reaction mechanism from autoignition to the occurrence of knocking is still not fully understood. The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.

The aim of this research was to investigate the mechanism causing autoignition and the effect of exhaust gas recirculation (EGR) on combustion by detecting the behavior of the OH radical and other excited molecules present in the flame in a spark ignition engine. The test equipment used was a 2-cycle engine equipped with a Schnürle scavenging system. Using emission spectroscopy, the behavior of the OH radical was measured at four locations in the end zone of the combustion chamber. The OH radical plays an important role in the elemental reactions of hydrocarbon fuels. When a certain level of EGR was applied according to the engine operating conditions, the unburned gas became active owing to heat transfer from residual gas near the measurement positions on the exhaust port side and the influence of excited species in the residual gas, and autoignition tended to occur.

The purpose of this research was to obtain a better understanding of engine knocking phenomena. Measurements were made of the behavior of formaldehyde (HCHO), an important intermediate product of cool flame reactions, and of the HCO radical, characterized by distinctive light emission during blue flame reactions. The test engine was operated on a blended fuel (50 RON) of n-heptane and iso-octane. Simultaneous measurements were made of the behavior of HCHO and the OH radical using absorption spectroscopy and of the behavior of HCO and OH radicals using emission spectroscopy. Absorbance spectroscopic measurements revealed behavior thought to correspond to the passage of a cool flame and emission spectroscopic measurements showed behavior thought to correspond to the passage of a blue flame.

Emission intensity was measured at a wavelength of 395 2 nm (corresponding to the characteristic spectrum of the HCHO radical) and absorbance was measured at 306 4 nm (corresponding to that of the OH radical). The emission intensity and absorbance waveforms recorded during engine operation on n-heptane show behavior indicative of the passage and degeneracy of cool flame in the preflame reaction interval. As the combustion chamber wall temperature approached an overheated state in the transition from normal combustion to knocking operation different preflame reaction behavior was observed which is thought to correspond to the presence of a negative temperature coefficient region related to the ignition delay time.

This study examined the effects of fuel composition and intake pressure on two-stage high temperature heat release characteristics of a Homogeneous Charge Compression Ignition (HCCI) engine. Light emission and absorption spectroscopic measurement techniques were used to investigate the combustion behavior in detail. Chemical kinetic simulations were also conducted to analyze the reaction mechanisms in detail. Blended fuels of dimethyl ether (DME) and methane were used in the experiments. It was found that the use of such fuel blends together with a suitable intake air flow rate corresponding to the total injected heat value gave rise to two-stage heat release behavior of the hot flame, which had the effect of moderating combustion. The results of the spectroscopic measurements and the chemical kinetic simulations revealed that the main reaction of the first stage of the hot flame heat release was one that produced CO from HCHO.

This study investigated the influence of EGR and spark advance on knocking under high compression ratio, ultra-lean mixture and supercharged condition using premium gasoline as a test fuel. A high-compression ratio, supercharged single cylinder engine was used in this experiment. As a result, the period from ignition to autoignition was prolonged. In addition, knock intensity was drastically reduced. In other words, it is inferred that by combining an appropriate amount of EGR and spark advance, high efficiency operation avoiding knocking can be realized.

The application of emulsified fuel for diesel engines is expected to reduce NOx and soot simultaneously. The purpose of this study is to clarify the influence of water content in emulsified fuel and fuel injection timing on diesel engine performance. The engine performance of emulsified fuel was compared with the water injection method. In the water injection test, water was injected to intake manifold and diesel fuel was directly injected into combustion chamber. Two emulsified fuels of which mixing ratio of water and emulsifier to diesel fuel were 15 and 30 vol.% were tested. Engine performance and exhaust gas emission of water injection method were almost similar to those of diesel fuel, so that water presented in combustion chamber had almost no influence on engine performance. Therefore, it can be considered that the micro explosion of fuel droplet enhanced the fuel atomization and mixing of fuel and air.

Attention has recently been focused on homogeneous charge compression ignition combustion (HCCI) as an effective combustion process for resolving the essential nature of combustion. Meanwhile, dimethylether (DME) has attracted interest as a potential alternative fuel for compression ignition engines. Authors measured the combustion process of DME HCCI by using a spectroscopic method. A diesel engine was used as the test engine. The results of these analyses showed that changes in the compression ratio, intake air temperature and equivalence ratio influenced the ignition timing in the HCCI combustion process. This paper discusses these effects in reference to the experimental and calculated results.